Asian Journal of Research in Chemistry

Krishan Kumar ¹, J. B. Dahiya ¹

Affiliations
1 Department of Chemistry, Guru Jambheshwer University of Science and Technology, Hisar, IN

Abstract

The effect of intumescent on the thermal degradation and flammability of cotton fabric has been studied in this investigation. The intumescent formulation containing ammonium polyphosphate, melamine, pentaerythritol and metal salts was used for coating the cotton fabric to make it flame retarded. The Thermal analysis (TG and DSC) in nitrogen atmosphere was carried out to study the thermal behaviour of coated cotton. Char yield of cotton fabric at 600 ℃ in nitrogen atmosphere was found increased from 12.8% to 25.4% on coating. The limiting oxygen index value for cotton fabric was found increased from 18.0% to 28.0% on coating with intumescent formulation (40 % w/w of cotton). The increase in char yield and LOI value justified the flame retarding behavior of coated cotton fabric.

Keywords

Flame-Retardant, Cotton, Intumescent, Thermal Degradation, Char Yield, Limiting Oxygen Index.

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J. B. Dahiya ¹, Krishan Kumar ¹

Affiliations
1 Department of Chemistry, Guru Jambheshwar University of Science and Technology, Hisar-125001, IN

Abstract

Industrial growths during the last century have led to the use of cellulosics for everyday household and office items (e.g. furniture, fabrics, automotive parts, housings for electronic equipment etc). But high flammability of such materials means that their occurrence could create a fire risk and hazard. Therefore, required fire safety standard needs the materials to be flame retarded. In the present study, the intumescent formulation containing ammonium polyphosphate, melamine, pentaerythritol and nanoclay was used for coating the cotton fabric to make it flame retarded. Thermal analysis in nitrogen atmosphere was carried out to study the thermal behaviour of coated fabric. Limiting oxygen index (LOI) study was also carried out to evaluate the flammability behaviour of the cotton fabric. Char yield of cotton fabric was found increased from 12.8 to 27.4% on coating with Intumescents containing nanoclay at 600 °C in nitrogen atmosphere. The LOI value for cotton fabric increased from 18 to 22.1% on coating with intumescent-nanoclay formulation.

Keywords

Nanoclay, Flame-Retardant, Cotton, Intumescent, Thermal Degradation, Char Yield.

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